The Glock 17 is carried by Victor in Season 4's premiere "Box Cutter" (S4E01).
Heckler & Koch Mark 23
A Heckler & Koch Mark 23 is used by Mike Ehrmantraut (Jonathan Banks) again in "Bullet Points" (S4E04) to take out a pair of Ciudad Juárez cartel gunmen who ambush a refrigerated truck transporting methamphetamine.
Beretta 92FS Inox
In "Salud" (S4E10), Mike takes a Beretta 92FS Inox from one of Don Eladio's (Steven Bauer's) henchmen. His Beretta appears to be one of the later production model Inox versions (which has black controls).
Ruger KP89
Walter White first tries out a Ruger KP89 while talking with the illegal arms dealer Lawson (Jim Beaver) in "Thirty-Eight Snub" (S4E02).
Taurus PT99
In "Salud" (S4E10), after Mike tells him to "make [himself] useful" by getting himself a gun, Jesse Pinkman (Aaron Paul) grabs a Taurus PT99 AFS from a dead henchman. He later uses it while escaping Don Eladio's compound.
Lawson's Gun Case
In "Thirty-Eight Snub" (S4E02), the arms dealer Lawson (Jim Beaver) has a case open that contains several pistols.
Revolvers
Ruger LCR
Walter White purchases a Ruger LCR from an illegal arms dealer (Jim Beaver) along with a leather I.W.B. holster in "Thirty-Eight Snub" (S4E02). The arms dealer recommends he load it with 158 grain hollow points for good stopping power, and also recommends he not cross draw unless he is sitting down. Although the Ruger is seen quite a bit in season 4, Walt only successfully uses it once. Walt later retrieves one from the soda machine in the car wash in the episode Confessions, and uses it to search his house for Jesse.
Taurus Model 85
A Taurus Model 85 is loaned to Jesse in "Problem Dog" (S4E07) and later drawn by Mike during the sniper attack in "Bug" (S4E09).
Submachine Guns
Heckler & Koch MP5K
In "Bullet Points" (S4E04), a refrigerated truck guarded by Mike (Jonathan Banks) is ambushed and then shot up by two Ciudad Juárez cartel enforcers, both of whom are armed with Heckler & Koch MP5Ks.
Assault Rifles
M4A1 Carbine
The M4A1 Carbine is seen in the hands of one of Gustavo Fring's (Giancarlo Esposito's) gunmen riding in the back of the refrigerated truck in "Cornered" (S4E06).
Colt Model 933
In "Cornered" (S4E06), the other of the two mercenaries guarding the refrigerated truck is armed with a Colt Model 933, the shorter-barreled version of the M4A1 carried by his accomplice.
Remington 700 Bolt-action Rifle
In "Bug" (S4E09), Cartel enforcer Gaff uses a version of the Remington 700 bolt-action rifle with Badger ordnance BDM (Badger Detachable Magazine) bottom metal, and Barrett BORS equipped scope to kill one of Gus's henchmen, and fires several more shots at Gus.