All 4 One is the collective name for the four signature guns of Jeanne, Bayonetta's enemy in the original Bayonetta game later ally in the second who appears in Ultimate as a Spirit. These guns have traces of features from the Luger P08 evident in them. Despite having an alternate costume based on Jeanne, Bayonetta does not use the All 4 One pistols for she still keeps her Love is Blues instead.
Colt M1911A1
Naked Snake's Spirit depicts him with his iconic highly modified Colt M1911A1 with a silencer attached.
The Desert Eagle Mark XIX with a 10 inch barrel and a scope from Metal Gear Solid 4 is carried by Meryl Silverburgh's Spirit.
Heckler & Koch Mark 23
Much like during his previous appearance in Brawl, Snake keeps a Heckler & Koch Mark 23 in his holster but it cannot be used.
"Love is Blue"
Love is Blue is the collective name of Bayonetta's main pistols from Bayonetta 2 (which takes inspiration from the Mauser C96) and is appropriately featured in her alternate costumes based on her appearance from that game and is used in a number of her attacks.
Norinco Type 54
Joker from Persona 5 was added to the game as DLC on April 17, 2019 as part of the "Challenger Pack 1". As in his home series, his main firearm is a Norinco Type 54 with a silver finish (known in Persona 5 as the Makaranov; in that game an airsoft replica operating like a real weapon due to the rules of the Metaverse). The Type 54 is Joker's Neutral Special move and can be fired in alternate directions. When Joker's Persona Arsene comes out to fight alongside him after filling the Rebellion Gauge, the Type 54 becomes capable of rapid semi-automatic fire. It never runs out of ammunition or needs to be reloaded.
"Scarborough Fair"
Highly based off of the Remington 1866 Derringer, Scarborough Fair is the collective name of Bayonetta's signature pistols from the first game in her eponymous series and are used in her alternate costumes that come from her appearance in it. In Super Smash Brothers, the difference between these and the Love is Blue are merely cosmetic as both weapons use the same attack animations and do the same amount of damage.
Shansi Type 17
EVA from Metal Gear Solid 3 appears in the game as a Spirit with her Shansi Type 17 drawn.
"Tornado-6"
Enhancing Major Ocelot's Spirit after leveling it up to Level 99 will turn the Spirit into the Phantom Pain incarnation of Revolver Ocelot with his "Tornado-6" drawn. In Phantom Pain, the Tornado-6 is actually an altered Uragan-5 which in turn takes influence from Mateba series revolvers, while having the hexagonal cylinder design of the Chiappa Rhino series, and a break-action design similar to the MP-412 REX. Curiously, the Tornado-6 here seems to have a nickel finish in contrast to its appearance in Phantom Pain. The vector used by the Spirit is also used in an icon you can place on your Smash Tag as well.
Rifles
AR-15 Variant
Snake's Fighter Spirit, which is unlocked after you complete his Classic campaign for the first time, depicts him holding an AR-15 style rifle with an M16A2 style handguard and aftermarket sights. The angle the rifle is being held at makes it admittedly difficult for a more positive identification. Cartoonish M16s also appear in the Tank & Infantry Spirit.
Blunderbuss
Newcomer King K. Rool's neutral special has him using a Blunderbuss with a comically oversized muzzle, the weapon being a callback to one of his moves in Donkey Kong Country 2: Diddy's Kong Quest. The Blunderbuss can not only fire cannonballs but can vacuum up either the cannonball or other opponents and shoot them back out in different directions.
"MRS-4"
The FAL-style "MRS-4" from Metal Gear Solid V is seen in the Spirit of Big Boss (or more specifically Venom Snake), which is unlocked after you enhance the Spirit of Naked Snake upon reaching Level 99 with it and is also seen on a Smash Tag icon that uses the same vector for Venom Snake. The rifle in turn is influenced by the Beretta SCP-70/90, the Imbel MD 97, the FN FNC, the SR 88, the Daewoo K2, and the Gwinn Firearms Bushmaster Rifle.
The aforementioned Gekko Spirit/stage scenery also have Browning M2HBs mounted on them.
C4
Both the regular and butterfly versions of the C4 return as Snake's down special, the only difference is this time it now has an obvious red light after being placed. Both versions of the C4 do the same amount of damage.
M18 Smoke Grenade
Snake uses an M18 smoke grenade to signal the beginning of his new Final Smash called Covering Fire, which signals a rocket barrage after Snake marks his location.
M224 Mortar
The M224 Mortar from Metal Gear Solid 4 returns as Snake's up smash.
M67 Hand Grenade
The M67 hand grenades from Brawl return as Snake's neutral special, only this time they seem to be more oversized than in Brawl as the grenades are too big for Snake's hands, although this is likely so they can be more easily seen during gameplay.
"Nikita Missile Launcher"
The "Nikita missile launcher" from Metal Gear Solid 2, which in turn resembles a FIM-92 Stinger, returns as Snake's side special.
RPG-7
The RPG-7 with a PGO-7 scope returns from Brawl as Snake's side smash.